Unfortunately, characters created on one Home World cannot be transferred to separate Worlds using a single application. You must submit individual requests for each character you wish to transfer to multiple Worlds.
For additional questions regarding the Home World Transfer Service, please visit the following article:
http://support.na.square-enix.com/faqarticle.php?id=5382&la=1&kid=77415
FAQ Article: 68801
FAQ Category: [Service Fee] / FAQ Sub-category: [Options]